First Author:Lei Liu

Correspondence Author:Yuhong Liu, Qionglin Liang, Hongbin Sun

Co author:Yongjian Ai, Jifan Li, Junjie Zhou, Zibo Fan, Hongjie Bao, Ruihang Jiang,Zenan Hu, Jingting Wang, Ke Jing, Yue Wang

Journal:Iscience

Volume:8

Impact Factor:7.2

DOI number:10.1016/j.isci.2018.09.010

Affiliation of Author(s):Department of Chemistry, Northeastern University

Teaching and Research Group:物理化学

Place of Publication:UNITED STATES

Abstract:A multicomponent nanocatalyst system was fabricated for the transfer hydrogenation of nitrile compounds. This catalyst system contains palladium, copper, and iron, which are supported on the magnetite nanospheres, and the loading of palladium could be at the parts per million level. Palladium and copper contribute to the transformation of nitrile, and the product distribution highly depends on the alloying of Fe to Cu. The nitriles could be converted to primary amine by the Pd-Cu catalyst in the absence of Fe, whereas in the presence of Fe the products are secondary amines with high selectivity. This could be attributed to the electronic modulation of iron to copper. A variety of nitriles have been transformed to the corresponding primary or secondary amines with high selectivity, and the TOF reaches 2,929 hr1 for Pd. Furthermore, the catalyst could be recycled by an external magnetic field and reused five times without severe activity loss

Document Code:WOS:000449736300007

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:61-73

Translation or Not:no