First Author:Ruihang Jiang

Correspondence Author:Zhangpei Chen, Hong-bin Sun

Co author:Kun Zhan, Lei Liu, Junjie Zhou, Yongjian Ai, Shuang Li, Hongjie Bao, Ze'nan Hu, Li Qi, Jingting Wang

Journal:Tetrahedron Letters

Issue:34

Volume:59

Impact Factor:1.6

DOI number:10.1016/j.tetlet.2018.07.039

Affiliation of Author(s):Department of Chemistry, Northeastern University

Teaching and Research Group:物理化学

Place of Publication:ENGLAND

Abstract:The vinyl benzoate derivatives were successfully synthesized by the transvinylation reactions that vinyl group transferred from vinyl acetate to aromatic carboxylic acids with the recoverable catalyst RhCl3 center dot 3H(2)O. This catalyst features air stable and tolerance of water, good reusable ability, meanwhile, shows high selectivity for aromatic carboxylic acid in the presence of phenolic hydroxyl. With this method, a variety of vinyl benzoate derivatives can be produced with up to 95% yield.

Key Words:Rhodium chlorideTransvinylationVinyl benzoateVinyl esterTransesterification

Document Code:WOS:000441489300011

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:3279-3282

ISSN No.:0040-4039

Translation or Not:no