Synthesis and Molecular Structures of BINOL Complexes: An STM Investigation of 2D Self-Assembly

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First Author:Xianghua Zeng

Correspondence Author:Ke Deng,Qingdao Zeng,Jingli Xie

Co author:Shaoqing Chang, Ke Deng, Junyong Zhang, Hongbin Sun

Journal:Crystal Growth & Design

Issue:7

Volume:15

Impact Factor:3.2

DOI number:10.1021/acs.cgd.5b00143

Affiliation of Author(s):Department of Chemistry, Northeastern University

Teaching and Research Group:物理化学

Place of Publication:UNITED STATES

Abstract:Three new (R)-BINOL complexes have been prepared. 2D self-assembly has been observed in the system consisting of crystalline (R)-BINOL derivatives (guest) and 1,3,5-tris(10-carboxydecyloxy)-benzene (host) by means of the scanning tunneling microscopy (STM) technique. Density functional theory (DFT) calculations help to reveal the assembly on the HOPG surface.

Key Words:Hydrocarbons,Molecules,Reaction products,Scanning tunneling microscopy,Supramolecular chemistry

Document Code:WOS:000357435800003

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:3096-3100

ISSN No.:1528-7483

Translation or Not:no