孙宏滨

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东北大学理学院化学系教授、博士生导师,研究领域包括电化学储能、氢能、催化化学、精细化学品合成工艺、复合纳米材料、水处理等。主持国家重点研发计划课题、国家自然科学基金等多项国家级、省部级科研项目,以及多项横向项目。在Nat. Commun., Angew. Chem.,Adv. Funct. Mater.等国内外知名期刊发表论文130余篇,授...

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论文成果

Triple boost to improve the lithium storage performance of hierarchical porous carbon

发布时间:2023-11-01  点击次数:

第一作者:Na Ju

通讯作者:Hong-bin Sun

合写作者:Jiajing Wu,Jianghua Zhang, Yongjian Ai, Yao Wang, Xinyue Zhang,Ze-Nan Hu,Zejun Sun

发表刊物:Journal of Energy Storage

卷号:71

影响因子:8.9

DOI码:10.1016/j.est.2023.108099

所属单位:Department of Chemistry, Tsinghua University

教研室:物理化学

刊物所在地:Netherlands

摘要:Carbon materials have been favored as lithium-ion battery anodes in both research and commercial field. This work presents a simple, scalable production namely “triple-boost” method to synthesize hierarchical porous carbon anode for Li ion storage. The polymerization of acetylacetone (Hacac) forms the precursor of carbon, while nickel acetylacetonate (Ni(acac)2), Fe3O4 nanoparticles, and 5-phenyl tetrazole are mixed to the precursor as three boosters, which dramatically improve the performance of lithium-ion battery (LIB). The obtained hierarchical porous carbon anode material has a high charge capacity of 1125.2 mAh·g−1 at a current density of 0.1 A·g−1, and it also exhibits a high-rate performance of 523.3 mAh·g−1 at a current density of 5 A·g−1. Meanwhile, 1000 cycles under 0.5 A·g−1 current density indicates its long cycle life, as the capacity attenuation of each cycle is only 0.008 %.

关键字:Li-ion batteries (LIBs)Carbon nanotubeHierarchical porous carbonAnode materials

论文编号:WOS:001027473000001

学科门类:理学

一级学科:化学

页面范围:108099

ISSN号:2352-152X

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