第一作者：Yiming Wang

通讯作者：Gang Zhang,Hong-bin Sun

合写作者：Li Hong,Hu Zenan, Chen Xin,Sun Zejun,Ai Yongjian, Xu Wenjuan,Zhang Wenhui,Ding Kelong,Li Chengrui,Jiang Tong,Zhao Shuya, Wang Haipeng

发表刊物：Microporous and Mesoporous Materials

卷号：346

影响因子：4.8

DOI码：10.1016/j.micromeso.2022.112322

所属单位：Department of Chemistry, Northeastern University

教研室：物理化学

刊物所在地：NETHERLANDS

摘要：Designing and developing efficient synergistic catalytic systems has always been an exciting topic. In this work, a sandwich-type nanocomposite, UiO-66-NH2@Pt@PCN-222, was utilized as a synergistic catalytic system for the selective reduction of nitrobenzaldehydes to nitrobenzyl alcohols. Benefiting from the synergy of PCN-222 and Pt NPs, the catalyst can efficiently promote the formation of 10 nitrobenzyl alcohols under mild conditions within as short as 30 min. Moreover, the PCN-222 provides not only active sites but also protection for metal nano particles, so the catalyst remained intact activity in cycles. This work has reference significance for the con struction of synergistic catalytic systems.

关键字：Synergistic catalysis,Sandwich-type nanocatalyst,Selective transfer hydrogenation,Rate matching,Nitrobenzaldehydes

论文编号：WOS:000891769500006

学科门类：理学

一级学科：化学

页面范围：112322

ISSN号：1387-1811

是否译文：否