孙宏滨

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东北大学理学院化学系教授、博士生导师,研究领域包括电化学储能、氢能、催化化学、精细化学品合成工艺、复合纳米材料、水处理等。主持国家重点研发计划课题、国家自然科学基金等多项国家级、省部级科研项目,以及多项横向项目。在Nat. Commun., Angew. Chem.,Adv. Funct. Mater.等国内外知名期刊发表论文130余篇,授...

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Recovery of antimony using biological waste and stepwise resourcization as catalysts for both polyesterification and transfer hydrogenation

发布时间:2021-12-14  点击次数:

第一作者:Jiaxin Liang,Zenan Hu

通讯作者:Sun, Hongbin

合写作者:Feng, Yanru

发表刊物:Colloids and Surfaces A: Physicochemical and Engineering Aspects

卷号:635

影响因子:4.9

DOI码:10.1016/j.colsurfa.2021.128119

所属单位:Department of Chemistry, Northeastern University

教研室:物理化学

刊物所在地:NETHERLANDS

摘要:The recycle and reutilization of antimony in industrial sewage is an important issue. Here, we developed a protocol for the efficient antimony adsorption and the resourcization of the waste adsorbent. Following the concept of “treat waste by waste”, the adsorbent was produced with a kind of waste, pomelo peel, which was transferred to the biochar loaded ferric oxide (Fe3O4/BC) as the adsorbent. The Fe3O4/BC exhibited a fast procedure for the adsorption of antimony, and its maximum Sb(III) adsorption capacity reached 246.19 mg g 1 at 40 ◦C. Next, the re-utilization of the waste adsorbents was considered to avoid the secondary pollution of the solid waste. Taking the treatment of textile printing waste water as a real application, we realized the stepwise resourcization of the waste adsorbents as catalysts. The used adsorbents, Sb(III)/Fe3O4/BC, were extracted by KOH glycol solution and the eluent was directly used in synthesizing polyethylene terephthalate (PET). The remained part of the adsorbents could be converted into the catalyst for transfer hydrogenation (CTH) of nitroarenes. This work helps to achieve the waste-free application of antimony, and delivers an overall solution of Sb-containing waste water, which follows the concept of “turning waste into treasure”

关键字:Biochar,Adsorption of antimony,Polyethylene terephthalate,Nitroarenes,Resource utilization

论文编号:WOS:000733644100006

学科门类:理学

一级学科:化学

页面范围:128119

ISSN号:0927-7757

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