第一作者：Zenan Hu

通讯作者：Gang Zhang,Hong-bin Sun, Qionglin Liang

合写作者：Yongjian Ai, Lei Liu,Junjie Zhou, Gang Zhang, Hongqi Liu,Xiangyu Liu, Zhibo Liu, Jianshe Hu

发表刊物：Advanced Synthesis & Catalysis

期号：13

卷号：361

影响因子：9.4

DOI码：10.1002/adsc.201801611

所属单位：Department of Chemistry, Northeastern University

教研室：物理化学

刊物所在地：GERMANY

摘要：Control of chemoselectivity is a special challenge for the reduction of nitroarenes bearing one ormore unsaturated groups. Here, we report a flower-like Rh/α-FeOOH catalyst for the chemoselectivehydrogenation of nitrostyrene to vinylaniline over full conversion, which benefits the new functionalizedaminostyrene because the multisubstituted aminostyrenes are usually commercially unavailable. This catalystdoes not only show desirable selectivity for the vinylanilines, but also exhibits the inertness to various otherreducible groups over wide reaction duration. The catalytic selectivity for the reduction of the nitro grouptowards vinyl group was investigated by the control experiments and FT-IR analysis. We have found that theabundant hydroxyl groups in the α-FeOOH may contribute to the improvement of catalytic activity andselectivity. Furthermore, the catalyst exhibits excellent stability and keeps its catalytic performance even after6 cycles.

关键字：Hydrogen transfer; Hydroxyl Assisted; Nitrostyrenes; Nanoparticles; Heterogeneous catalysis

论文编号：WOS:000484142600014

学科门类：理学

一级学科：化学

页面范围：3146-3154

ISSN号：1615-4150

是否译文：否