孙宏滨

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东北大学理学院化学系教授、博士生导师,研究领域包括电化学储能、氢能、催化化学、精细化学品合成工艺、复合纳米材料、水处理等。主持国家重点研发计划课题、国家自然科学基金等多项国家级、省部级科研项目,以及多项横向项目。在Nat. Commun., Angew. Chem.,Adv. Funct. Mater.等国内外知名期刊发表论文130余篇,授...

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论文成果

Reusable rhodium catalyst for the selective transvinylation of sp2-C linked carboxylic acid

发布时间:2018-08-22  点击次数:

第一作者:Ruihang Jiang

通讯作者:Zhangpei Chen, Hong-bin Sun

合写作者:Kun Zhan, Lei Liu, Junjie Zhou, Yongjian Ai, Shuang Li, Hongjie Bao, Ze'nan Hu, Li Qi, Jingting Wang

发表刊物:Tetrahedron Letters

期号:34

卷号:59

影响因子:1.6

DOI码:10.1016/j.tetlet.2018.07.039

所属单位:Department of Chemistry, Northeastern University

教研室:物理化学

刊物所在地:ENGLAND

摘要:The vinyl benzoate derivatives were successfully synthesized by the transvinylation reactions that vinyl group transferred from vinyl acetate to aromatic carboxylic acids with the recoverable catalyst RhCl3 center dot 3H(2)O. This catalyst features air stable and tolerance of water, good reusable ability, meanwhile, shows high selectivity for aromatic carboxylic acid in the presence of phenolic hydroxyl. With this method, a variety of vinyl benzoate derivatives can be produced with up to 95% yield.

关键字:Rhodium chlorideTransvinylationVinyl benzoateVinyl esterTransesterification

论文编号:WOS:000441489300011

学科门类:理学

一级学科:化学

页面范围:3279-3282

ISSN号:0040-4039

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