东北大学主页平台孙宏滨--中文主页-- An Efficient Bismuth(III) Chloride-Catalyzed Synthesis of 1,1-Diarylalkenes via Friedel–Crafts Reaction of Acyl Chloride or Vinyl Chloride with Arenes

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孙宏滨

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东北大学理学院化学系教授、博士生导师，研究领域包括电化学储能、氢能、催化化学、精细化学品合成工艺、复合纳米材料、水处理等。主持国家重点研发计划课题、国家自然科学基金等多项国家级、省部级科研项目，以及多项横向项目。在Nat. Commun.， Angew. Chem.，Adv. Funct. Mater.等国内外知名期刊发表论文130余篇，授...

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论文成果

An Efficient Bismuth(III) Chloride-Catalyzed Synthesis of 1,1-Diarylalkenes via Friedel–Crafts Reaction of Acyl Chloride or Vinyl Chloride with Arenes

发布时间：2006-09-12 点击次数：

第一作者：Hongbin Sun

通讯作者：Ruimao Hua

合写作者：Songjie Chen, Yingwu Yin

发表刊物：Advanced Synthesis & Catalysis

期号：14

卷号：348

影响因子：4.4

DOI码：10.1002/adsc.200606157

所属单位：Department of Chemistry, Tsinghua University

教研室：物理化学

刊物所在地：GERMANY

摘要：In the presence of catalytic amount of bismuth(III) chloride, the reactions of acyl chlorides or vinyl chlorides with arenes afforded 1,1-diarylalkenes in 25–82 % isolated yield. In the case of the reaction of acyl chlorides with arenes, the procedure includes an initial Friedel–Crafts acylation, subsequent formation of vinyl chlorides and final Friedel–Crafts-type vinylation of another arene molecule with vinyl chloride. This paper reports the first Lewis acid-catalyzed cleavage of the CCl bond of vinyl chloride and its application in the synthesis of multiply subtituted alkenes.

关键字：acyl chlorides; arenes; bismuth(III) chlo-ride; 1,1-diarylalkenes; Friedel–Crafts reaction; vinylchlorides

论文编号：WOS:000240707900019

学科门类：理学

一级学科：化学

页面范围：1919-1925

ISSN号：1615-4150

是否译文：否

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