孙宏滨

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东北大学理学院化学系教授、博士生导师,研究领域包括电化学储能、氢能、催化化学、精细化学品合成工艺、复合纳米材料、水处理等。主持国家重点研发计划课题、国家自然科学基金等多项国家级、省部级科研项目,以及多项横向项目。在Nat. Commun., Angew. Chem.,Adv. Funct. Mater.等国内外知名期刊发表论文130余篇,授...

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论文成果

Highly Efficient Nitration of Phenolic Compounds in Solid Phase or Solution Using Bi(NO3)3·5H2O as Nitrating Reagent

发布时间:2005-09-29  点击次数:

第一作者:Hong-Bin Sun

通讯作者:Ruimao Hua, Yingwu Yin

合写作者:Ruimao Hua, Yingwu Yin

发表刊物:Journal of Organic Chemistry

期号:22

卷号:70

影响因子:3.3

DOI码:10.1021/jo0514669

所属单位:Department of Chemistry, Tsinghua University

教研室:物理化学

刊物所在地:UNITED STATES

摘要:Bi(NO3)3·5H2O was used as an efficient nitrating reagent in the nitration of phenolic compounds to give nitrated phenols in good to high yields. The nitration reaction proceeded smoothly by grinding 1 equiv of phenol, 2-methylphenol, 4-methylphenol, or 4-chlorophenol and Bi(NO3)3·5H2O, and the nitration of other phenolic compounds could be performed in acetone at ambient temperature (22−30 °C).

关键字:Aromatic compounds,Chemical reactions,Hydrocarbons,Organic reactions,Reagents

论文编号:WOS:000232909300065

学科门类:理学

一级学科:化学

页面范围:9071-9073

ISSN号:0022-3263

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