First Author:Li Shuang

Correspondence Author:Ju Jia,Sun Hongbin

Co author:Xiang Heng,Jiang Ruihang,Jiao Pengchong,Yuan Hualei,Cai, Huaqiang

Title of Paper:Stereoselective Vinylation under Mild Metal-Free Conditions to Synthesize N-Vinylazoles

Journal:Chinese Journal of Organic Chemistry

Issue:6

Volume:38

Impact Factor:2.9

DOI Number:10.6023/cjoc201710009

Institution:Department of Chemistry, Northeastern University

Teaching and Research Group:物理化学

Place of Publication:PEOPLES R CHINA

Summary:A metal-free synthetic protocol for N-vinylazoles has been developed. Twenty-two structurally diversed N-vinylazoles including 15 new compounds are obtained with good to high yield at near room temperature, and all of products consist trans-alkene moieties with high stereoselectivity.

Key Words:metal-free; C—N coupling; vinylation; azoles; stereoselectivity

Document Code:WOS:000440497100021

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:1493-1499

ISSN:0253-2786

Translation or Not:No