First Author:Hongbin Sun

Correspondence Author:Hongbin Sun, Xuan Qi

Co author:Sun, Hongbin, Sun, Yuanhua, Tian, Xiaohua, Zhao, Yunxia,Qi, Xuan

Title of Paper:Nanosized Ferric Hydroxide Catalyzed C-O Cross-Coupling of Phenol and Halides to Generate Phenoxy Ether

Journal:Asian Journal of Chemistry

Issue:11

Volume:25

DOI Number:10.14233/ajchem.2013.14307

Institution:Department of Chemistry, Northeastern University

Teaching and Research Group:物理化学

Place of Publication:INDIA

Summary:The iron-based catalyst can effectively catalyze the phenolic hydroxyl C-O bond formation reaction to give the corresponding phenoxy ethers. The reaction of phenol and methyl chloroacetate, for example, gives phenoxy acetic acid methyl ester in 98 % yield under the optimal reaction conditions. Among the iron-based catalysts, nanosized ferric hydroxide prepared through sol-gel method gives the best catalytic activity.

Key Words:Catalysis, Nanosized ferric hydroxide, C-O cross-coupling, Phenoxy ether

Document Code:WOS:000325089600072

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:6189-6191

ISSN:0970-7077

Translation or Not:No