First Author:Hong-Bin Sun

Correspondence Author:Ruimao Hua, Yingwu Yin

Co author:Ruimao Hua, Yingwu Yin

Title of Paper:Highly Efficient Nitration of Phenolic Compounds in Solid Phase or Solution Using Bi(NO3)3·5H2O as Nitrating Reagent

Journal:Journal of Organic Chemistry

Issue:22

Volume:70

Impact Factor:3.3

DOI Number:10.1021/jo0514669

Institution:Department of Chemistry, Tsinghua University

Teaching and Research Group:物理化学

Place of Publication:UNITED STATES

Summary:Bi(NO3)3·5H2O was used as an efficient nitrating reagent in the nitration of phenolic compounds to give nitrated phenols in good to high yields. The nitration reaction proceeded smoothly by grinding 1 equiv of phenol, 2-methylphenol, 4-methylphenol, or 4-chlorophenol and Bi(NO3)3·5H2O, and the nitration of other phenolic compounds could be performed in acetone at ambient temperature (22−30 °C).

Key Words:Aromatic compounds,Chemical reactions,Hydrocarbons,Organic reactions,Reagents

Document Code:WOS:000232909300065

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:9071-9073

ISSN:0022-3263

Translation or Not:No