First Author:Hong-Bin Sun

Correspondence Author:Ruimao Hua

Co author:Biao Li, Yingwu Yin

Title of Paper:An Efficient and Selective Hydroarylation of Styrenes with Electron-Rich Arenes, Catalyzed by Bismuth(III) Chloride and Affording Markovnikov Adducts

Journal:European Journal of Organic Chemistry

Issue:18

Volume:2006

Impact Factor:2.5

DOI Number:10.1002/ejoc.200600390

Institution:Department of Chemistry, Tsinghua University

Teaching and Research Group:物理化学

Place of Publication:GERMANY

Summary:In the presence of BiCl3, the hydroarylation of styrenes with electron-rich arenes afforded Markovnikov adducts selectively in good to high yields. Under arene-free conditions, the intermolecular hydroarylation of α-substituted styrenes and subsequent intramolecular hydroarylation produced the cyclic dimers of α-substituted styrenes in good yields.

Key Words:Arenes, Bismuth trichloride, Dimerization, Hydroarylation, Markovnikov adduct

Document Code:WOS:000240662900020

Discipline:Natural Science

First-Level Discipline:Chemistry

Page Number:4231-4236

ISSN:1434-193X

Translation or Not:No