第一作者:Wenjuan Xu
通讯作者:Hong-bin Sun
合写作者:Yanru Feng, Zejun Sun, Liutao Guo, Chengrui Li, Hong Li, Yiming Wang
论文名称:P-induced bottom-up growth of Fe-doped Ni12P5 nanorod arrays for urea oxidation reaction
发表刊物:Journal of Colloid and Interface Science
卷号:633
DOI码:10.1016/j.jcis.2022.11.109
所属单位:DepartmentofChemistry,NortheasternUniversity
教研室:物理化学
刊物所在地:UNITED STATES
摘要:Synthesisofregularmorphologycatalystswithself-growingsubstratesisoneoftheeffectivemethodsto
solvetheproblemofeasysheddingofheterogeneouscatalysts. Inthisstudy,Fe-dopedNi12P5nanorods
werepreparedbydepositing1,10-bis (diphenylphosphine) ferrocene (DPPF) onN-dopedC/NF. The
bottom-upgrowthofthenanorodisascribedtothepreferentialadsorptionofDPPFwithaPsitetoNF
that issurface-dopedwiththesolid-solvingC, andthelengthofnanorodscanreachtensofmicrons
andhasgoodrobustness. TheN-dopedcarbon-constrainedrod-shapedFe-dopedNi12P5catalyst (Fe
Ni12P5/NdC/NF-800)thatgrowsonNFhasexcellentcatalyticperformancefortheureaoxidationreaction.
Inaddition,thecurrentdensitycanbemaintainedashighas100mAcm2andthecurrentattenuationis
weakfor12h, andtherodshaperemainsgood.Thisworkprovidesanewideaforsynthesizingself
growingcatalystswithregularmorphologytoimprovetheperformanceofheterogeneouscatalysts.
关键字:Bottom-up growth,Nanorod Ni12P5,Phosphorus inductionFe dopingUrea oxidation reaction
论文编号:WOS:000901458400006
学科门类:理学
一级学科:化学
页面范围:746-753
ISSN号:0021-9797
是否译文:否
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