王义松
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摘要:Mesoporous ZSM-5 zeolite as the adsorbent supporting material was synthesized from rice husk ash (RHA), and then impregnated with polyethylenimine (PEI) for amine functional modification. A series of adsorbents (ZSM-5-PEI-X) with different PEI loading ratios were characterized by XRD, FTIR, TGA/DTG, nitrogen adsorption-desorption, SEM and EDX techniques. The measurement of the adsorption capacity at different temperatures was indicated that ZSM-5-PEI-30 had the highest adsorption capacity at 120 °C (1.96 mmol/g). The experimental data were fitted by adsorption kinetic models and isotherm models, indicated that fractional-order model and the Dual-site langmuir model can be used to describe the adsorption mechanism and predict the adsorption performance. The high CO2 adsorption selectivity and regeneration stability suggested that this adsorbent is a potential candidate in the adsorption and separation of CO2 in industrial flue gas.
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上一条:Wang, Y., Du, T., Zhou, L., Song, Y., Che, S., & Fang, X. (2018). Removal of Acid Red G dye from aqueous solutions by adsorption to MCM-41-layered double hydroxides composite. Korean Journal of Chemical Engineering, 35, 709-716.
下一条:Wang, Y., Du, T., Song, Y., Che, S., Fang, X., & Zhou, L. (2017). Amine-functionalized mesoporous ZSM-5 zeolite adsorbents for carbon dioxide capture. Solid State Sciences, 73, 27-35.