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    王义松

    • 副教授 硕士生导师
    • 教师拼音名称:WangYisong
    • 出生日期:1989-03-31
    • 电子邮箱:
    • 入职时间:2021-04-26
    • 学历:博士研究生毕业
    • 办公地点:知行楼610
    • 性别:男
    • 学位:博士
    • 毕业院校:东北大学
    • 学科:热能工程

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    Wang, Y., Du, T., Qiu, Z., Song, Y., Che, S., & Fang, X. (2018). CO2 adsorption on polyethylenimine-modified ZSM-5 zeolite synthesized from rice husk ash. Materials Chemistry and Physics, 207, 105-113.

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    摘要:Mesoporous ZSM-5 zeolite as the adsorbent supporting material was synthesized from rice husk ash (RHA), and then impregnated with polyethylenimine (PEI) for amine functional modification. A series of adsorbents (ZSM-5-PEI-X) with different PEI loading ratios were characterized by XRD, FTIR, TGA/DTG, nitrogen adsorption-desorption, SEM and EDX techniques. The measurement of the adsorption capacity at different temperatures was indicated that ZSM-5-PEI-30 had the highest adsorption capacity at 120 °C (1.96 mmol/g). The experimental data were fitted by adsorption kinetic models and isotherm models, indicated that fractional-order model and the Dual-site langmuir model can be used to describe the adsorption mechanism and predict the adsorption performance. The high CO2 adsorption selectivity and regeneration stability suggested that this adsorbent is a potential candidate in the adsorption and separation of CO2 in industrial flue gas.

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