王义松

  • 副教授 硕士生导师
  • 教师拼音名称:WangYisong
  • 出生日期:1989-03-31
  • 电子邮箱:
  • 入职时间:2021-04-26
  • 学历:博士研究生毕业
  • 办公地点:知行楼610
  • 性别:男
  • 学位:博士
  • 毕业院校:东北大学
  • 学科:热能工程

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Wang, Y., Du, T., Song, Y., Che, S., Fang, X., & Zhou, L. (2017). Amine-functionalized mesoporous ZSM-5 zeolite adsorbents for carbon dioxide capture. Solid State Sciences, 73, 27-35.

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摘要:ZSM-5 type zeolite with mesoporous structure was prepared and then amine-functionalized with tetraethylenepentamine (TEPA) by wet impregnation method to form a series of CO2 adsorbents (ZTx). The structural properties of ZSM-5 and ZTx were characterized by XRD, FTIR, TGA/DTG, nitrogen adsorption/desorption, SEM and EDX techniques. The adsorption capacity of the adsorbents with different amine loading was measured at a temperature from 40 to 100 degrees C and the adsorption capacity of ZT7 was 1.80 mmol/g at 100 degrees C. The adsorption process and mechanism were studied by fitting the experimental data used the three adsorption kinetic models, and a complex physical and chemical mixing process was produced as the amine entered the surface and pore size of the zeolite. The high adsorption selectivity at 10% CO2 concentration and the stability of the five adsorption desorption cycles indicated that ZT7 is a suitable and promising CO2 adsorbent for the purification of industrial flue gas.

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